1,3,5-Tri (1H-1,2,3-triazol-5-yl) benzene is a tritopic triazole-bridged ligand (H 3 BTTri) that forms a sodalite-type metal-organic framework with coordinatively unsaturated cobalt (II) centers. This framework exhibits selective O 2 -binding capacity over N 2. 1,3,5-Tri (1H-1,2,3-triazol-5-yl) benzene can be used for the synthesis of metal-organic framework (MOF)-related materials [1].
In Vitro, 1,3,5-Tri(1H-1,2,3-triazol-5-yl)benzene-derived activated Co-BTTri (195, 213, 223 K) exhibits preferential O2 adsorption over N2[1]. 1,3,5-Tri(1H-1,2,3-triazol-5-yl)benzene-derived activated Co-BTTri (10 cycles; 24 h humid air exposure) retains full O2 adsorption capacity, crystallinity, and surface area after 10 adsorption/desorption cycles and 24 h exposure to 90% relative humidity air followed by reactivation[1].
References:
[1]. Xiao DJ, et al. Selective, Tunable O2 Binding in Cobalt(II)-Triazolate/Pyrazolate Metal-Organic Frameworks. J Am Chem Soc. 2016;138(22):7161-7170.
In Vitro, 1,3,5-Tri(1H-1,2,3-triazol-5-yl)benzene-derived activated Co-BTTri (195, 213, 223 K) exhibits preferential O2 adsorption over N2[1]. 1,3,5-Tri(1H-1,2,3-triazol-5-yl)benzene-derived activated Co-BTTri (10 cycles; 24 h humid air exposure) retains full O2 adsorption capacity, crystallinity, and surface area after 10 adsorption/desorption cycles and 24 h exposure to 90% relative humidity air followed by reactivation[1].
References:
[1]. Xiao DJ, et al. Selective, Tunable O2 Binding in Cobalt(II)-Triazolate/Pyrazolate Metal-Organic Frameworks. J Am Chem Soc. 2016;138(22):7161-7170.